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Novel catalytic membranes for selective reactions
Authors:Vankelecom  Ivo F.J.  Vercruysse  Karen A.L.  Neys  Patricia E.  Tas  Diedrik W.A.  Janssen  Kristien B.M.  Knops-Gerrits  Peter-Paul  Jacobs   P.A.
Affiliation:(1) Department of Interface Chemistry, Centrum voor Oppervlaktechemie en Katalyse, K.U. Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee, Belgium E-mail:
Abstract:A survey is given of the potentials of a new kind of catalytic membranes consisting of a catalyst that is immobilised in a dense polymer matrix. When homogeneous, catalytically active complexes are occluded, these membranes constitute a new way of heterogenation. In the case of solid state catalysts, these composite membranes can improve the activity of the catalyst by changing sorption or by allowing experimental set-ups in which solvents become redundant. This revised version was published online in June 2006 with corrections to the Cover Date.
Keywords:transition metal complexes  chiral catalysts  Ti-containing zeolites  polymers  PDMS  catalytic membrane reactor
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