| 以季戊四醇为核的超支化不饱和聚酰胺酯的合成 |
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| 引用本文： | 王秀侠,马家举,王战思. 以季戊四醇为核的超支化不饱和聚酰胺酯的合成[J]. 安徽化工, 2010, 36(3): 34-36. DOI: 10.3969/j.issn.1008-553X.2010.03.011 |
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| 作者姓名： | 王秀侠 马家举 王战思 |
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| 作者单位： | 安徽理工大学化学工程学院,安徽,淮南,232001;安徽理工大学化学工程学院,安徽,淮南,232001;安徽理工大学化学工程学院,安徽,淮南,232001 |
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| 摘 要： | 以顺丁烯二酸酐（MA）和二乙醇胺（DEA）为原料合成超支化不饱和聚酰胺酯AB2型单体。通过季戊四醇和AB2型单体进行酯化反应合成支化不饱和聚酰胺酯HBP。考查了反应温度、催化剂用量、反应时间对反应产率的影响。最佳工艺条件为：温度140℃,反应时间5h,催化剂对甲苯磺酸用量为反应物量的1.5%。
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| 关 键 词： | 季戊四醇 超支化不饱和聚酰胺酯 合成 |
The Synthesis of Pentaerythritol-based Hyperbranched Unsaturated Poly(amide ester) |
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| WANG Xiu-xia,MA Jia-ju,WANG Zhan-si. The Synthesis of Pentaerythritol-based Hyperbranched Unsaturated Poly(amide ester)[J]. Anhui Chemical Industry, 2010, 36(3): 34-36. DOI: 10.3969/j.issn.1008-553X.2010.03.011 |
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| Authors: | WANG Xiu-xia MA Jia-ju WANG Zhan-si |
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| Affiliation: | WANG Xiu-xia,MA Jia-ju,WANG Zhan-si(Chemical Engineering School,Anhui University of Science and Technology,Huainan 232001,China) |
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| Abstract: | AB2 type-hyperbranched poly(amide ester)monomer were synthesized by use of maleic anhydride(MA) and diethanolamine(DEA).The hyperbranched unsaturated poly(amide ester)(HBP)was synthesized by pentaerythritol and AB2 type-monomer.The affection of the reaction conditions,such as the amount of catalyst,temperature and the reaction time on the reaction were studied.The experimental result showed that the optimum conditions were as follows:pentaerythritol reacted with AB2 type-monomer for 5h at 140℃ with p-toluenesulfonic acid which quality was 1.5% of reactants’. |
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| Keywords: | pentaerythritol hyperbranched unsaturated poly(amide ester) synthesis |
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