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Useful direct conversion of tetrahydropyranyl ethers of fatty alcohols into fatty acids
Authors:Régine Gruiec  Nicolas Noiret  Henri Patin
Affiliation:(1) LCOSN, URA 1467, ENSCR, Avenue du Général Leclerc, 35700 Rennes-Beaulieu, France
Abstract:Tetrahydro-2-pyranyl ethers from fatty primary alcohols can be converted in a one-step procedure into the corresponding carboxylic acids in high yields. This process avoids the synthesis of symmetrical esters, particularly for long-chain compounds. This reaction proved to be useful, for instance, to produce polyunsaturated fatty acids immediately before their biological testing.
Keywords:Oxidation  polyunsaturated fatty acids  tetrahydropyranyl ethers
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