| 环戊二烯加氢宏观动力学的研究 |
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| 作者姓名： | 郭世卓 徐泽辉 夏蓉晖 周飞 房鼎业 |
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| 作者单位： | [1]Shanghai Petrochemical Company Ltd., Shanghai 200540, China [2]College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China |
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| 摘 要： | The macrokinetics of hydrogenation of cyclopentadiene was investigated over Pdγ-Al2O3 catalyst. Experimental results showed that the relationship between the constituents and reaction time was in agreement with the characteristic of consecutive irreversible first-order reaction. Analysis on the reaction mechanism of selective hydrogenation of cyclopentadiene indicated that it is reasonable to express the hydrogenation rate of cyclopentadiene in the power law form. Parameters of the kinetic model were obtained by the Gauss-Newton method based on the experimental data. From the statistic test and residual error distribution the kinetic model was proved to be adequate.
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| 关 键 词： | 环戊二烯 环戊烯 加氢反应 宏观动力学 Pd/γ-Al2O3 催化剂 |
| 收稿时间： | 2004-10-11 |
| 修稿时间： | 2004-10-112005-06-01 |
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