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磺基甜菜碱的合成及其在水包油乳化钻井液中的应用
引用本文:邓小刚,罗飞,马丽华,席凤林,罗玉财,殷祥英,孙宗曼. 磺基甜菜碱的合成及其在水包油乳化钻井液中的应用[J]. 钻井液与完井液, 2017, 34(3): 33-38. DOI: 10.3969/j.issn.1001-5620.2017.03.006
作者姓名:邓小刚  罗飞  马丽华  席凤林  罗玉财  殷祥英  孙宗曼
作者单位:1. 西南石油大学化学化工学院, 成都 610500;
摘    要:水包油乳化钻井液作为一种重要的低密度水基钻井液体系,在低压油气层钻探中有着较为广泛的应用,针对目前该体系在深部地层使用过程中出现的抗温能力不足的问题,室内通过一步反应合成了不同碳链数的磺基甜菜碱,测定了其在高温处理后的表面性能变化情况,并将其引入水包油乳化钻井液中。实验结果表明,配制得到的钻井液性能良好,乳化稳定性好,在经过180~210℃热滚动16 h后,体系黏度、切力仍处于合理范围,高温高压滤失量均小于20 mL,满足基本要求;体系稳定性较好,无析油破乳现象发生;且具备一定的抗污染能力,抗水污染达15%,抗柴油污染达15%,抗钻屑污染达15%,抗盐污染达2%,因而能够满足深部低压油气层钻井的要求。 

关 键 词:水包油乳化钻井液   抗高温乳化剂   深井钻井   磺基甜菜碱   稳定性
收稿时间:2017-01-22

Sulfonated Betaine:Synthesis and Application in Oil-in-Water Emulsions
DENG Xiaogang,LUO Fei,MA Lihua,XI Fenglin,LUO Yucai,YIN Xiangying,SUN Zongman. Sulfonated Betaine:Synthesis and Application in Oil-in-Water Emulsions[J]. Drilling Fluid & Completion Fluid, 2017, 34(3): 33-38. DOI: 10.3969/j.issn.1001-5620.2017.03.006
Authors:DENG Xiaogang  LUO Fei  MA Lihua  XI Fenglin  LUO Yucai  YIN Xiangying  SUN Zongman
Affiliation:1. School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500;2. The Second Drilling Branch of CNPC Bohai Drilling Engineering Company Limited, Langfang, Hebei 065000;3. Department of Exploration of PetroChina Huabei Oilfield Company, Renqiu, Hebei 062550
Abstract:Oil-in-water emulsion drilling fluid is an important low-density water base drilling fluid and is widely used in drilling lowpressure reservoirs. To enhance the high temperature stability of the oil-in-water emulsion drilling fluid in deep well drilling, a sulfonated betaine with varied carbon chains was synthesized in laboratory and used in formulating emulsion drilling fluid after measuringthe change of its surface characteristics. Experimental results showed that the drilling fluid formulated had excellent rheology and good emulsion stability. After hot rolling at 180-210℃ for 16 hours, the viscosity and gel strengths of the drilling fluid were maintained in reasonable ranges. HTHP filter loss was less than 20 mL, satisfying the basic requirements as an emulsion drilling fluid. No oil separation and emulsification were found of the drilling fluid. The drilling fluid was resistant to contamination caused by 15% water, 15% diesel oil, 15% drilled cuttings, or by 2% salt, respectively, indicating that it was able to satisfy the needs for deep low pressure reservoir drilling.
Keywords:Oil-in-water emulsion drilling fluid  High temperature emulsifier  Deep drilling  Sulfonated betaine  Stability  
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