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热处理红-黄色翡翠的红外光谱分析
引用本文:项贤彪,张一翔,赖文波.热处理红-黄色翡翠的红外光谱分析[J].宝石和宝石学杂志,2011,13(2):31-37.
作者姓名:项贤彪  张一翔  赖文波
作者单位:1. 广东省地质科学研究所,广东广州,510080
2. 浙江省地质矿产研究所,浙江杭州,310007
基金项目:广东省地质勘查局2007年度地质科学研究基金资助项目(No.2007208)
摘    要:红-黄色翡翠是否经过热处理,其价值相差悬殊。随着市场对红-黄色翡翠的需求增加,鉴别其是否经过热处理是目前宝玉石鉴定的难点和热点问题。通过加热实验,利用红外光谱测试技术对加热前、后的红-黄色翡翠样品的红外光谱进行对比分析。结果表明,加热前、后的红-黄色翡翠样品的红外光谱具有不同的特征,主要表现为硬玉结构中OH的四组吸收峰强弱的变化:(1)吸收峰的强变化是在3 000~4 000 cm-1之间的峰型从加热前呈U型到加热后呈V型;(2)吸收峰的弱变化则是谱线略有改变,出现3 622~3 628 cm-1或3 670 cm-1附近的吸收峰,这些特征可作为红-黄色翡翠是否经过加热处理的辅助性诊断指标。

关 键 词:红外光谱  热处理  红-黄色翡翠

An Analysis of Infrared Spectra of Red-yellow Jadeites by Heat Treatment
XIANG Xian-biao,ZHANG Yi-xiang,LAI Wen-bo.An Analysis of Infrared Spectra of Red-yellow Jadeites by Heat Treatment[J].Journal of Gems & Gemmology,2011,13(2):31-37.
Authors:XIANG Xian-biao  ZHANG Yi-xiang  LAI Wen-bo
Affiliation:XIANG Xian-biao1,ZHANG Yi-xiang2,LAI Wen-bo1(1.Institute of Geological Sciences of Guangdong Province,Guangzhou 510080,China,2.Zhejiang Institute of Geologic and Mineral Resources,Hangzhou 310007,China)
Abstract:The value of red-yellow jadeites is very different depending on whether they have been processed with heat treatment.With an increasing demand for red-yellow jadeites,it has been a key as well as difficult issue to distinguish whether the jadeites are experienced heat treatments or not.In this paper,the heat treatment experiments are carried out on the red-yellow jadeites,and the infrared spectra of the jadeites before and after heat treatment are also compared.The results show that different spectral chara...
Keywords:infrared spectrum  heat treatment  red-yellow jadeite  
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