| 2，4，7-三硝基芴酮的合成 |
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| 引用本文： | 吉轩,张鑫,韩俊斌,张昭.2，4，7-三硝基芴酮的合成[J].精细化工中间体,2009,39(3):59-60,72. |
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| 作者姓名： | 吉轩 张鑫 韩俊斌 张昭 |
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| 作者单位： | 山西大学,化学化工学院,山西,太原,030006 |
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| 基金项目： | 山西省留学归国基金资助项目 |
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| 摘 要： | 以芴酮为原料，在水中与硝酸、硫酸的混合酸进行硝化反应制备2，4，7-三硝基芴酮，所得收率高于94％，纯度高于98％。与传统制备方法相比较，本法收率高，成本低，环境污染小，易实现工业化。所得产物的结构经过红外、核磁波谱的表征。
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| 关 键 词： | 芴酮 2 4 7-三硝基芴酮 硝化反应 |
Synthesis of 2,4,7-Trinitrofluorenone |
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| JI Xuan,ZHANG Xin,HAN Jun-bin,ZHANG Zhao.Synthesis of 2,4,7-Trinitrofluorenone[J].Fine Chemical Intermediates,2009,39(3):59-60,72. |
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| Authors: | JI Xuan ZHANG Xin HAN Jun-bin ZHANG Zhao |
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| Affiliation: | School of Chemistry and Chemical Engineering;Shanxi University;Taiyuan 030006;China |
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| Abstract: | 2,4,7-Trinitrofluorenone was synthesized from fluorenone in water by nitration with HNO3-H2SO4.The yield was higher than 94% and purity higher than 98%.Compared with the traditional preparation method,the newly-developed method has the advantages of high yield,low cast,less pollution,and easy to industrialize.The structure of product was characterized by IR and 1H NMR spectra. |
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| Keywords: | fluorenone 2 4 7-trinitrofluorenone nitration |
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