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La2Zr2O7 films on Cu–Ni alloy by chemical solution deposition process
Authors:ZM Yu  P Odier  L Ortega  L Zhou  PX Zhang  A Girard  
Affiliation:

aNortheastern University, Shenyang 110004, PR China

bNorthwest Institute for Nonferrous Metal Research, P.O. Box 51, Xi’An, Shaanxi 710016, PR China

cLaboratoire de Cristallographie, CNRS, 25 avenue des Martyrs, BP166, 38042 Grenoble Cedex, France

dLaboratoire d’Instrumentation et des Matériaux d’Annecy, BP806, 74016 Annecy, France

Abstract:Films of La2Zr2O7 (=LZO) have been formed by chemical solution deposition technique (CSD) on new bi-axially textured Cu–Ni alloy tapes based on rolled constantan (Cu55Ni45) Rabits. The precursor used was acetylacetonates treated in propionic acid (0.1–0.87 mol/l) and then deposited by spin-coating. The LZO film starts to crystallize above 850 °C, the film nucleates bi-axially textured on the substrate (with unit cell axis rotated 45° from those of the substrate). The top part of the film is not textured even after long annealing time at 1100 °C, but the interfacial part is bi-axially textured. Thus, synthesis of bi-axially textured films on Cu55Ni45 Rabits seems possible but more works are needed to optimize its properties.
Keywords:Texture  Solution deposition  Oxide film  Lanthanum zirconate
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