Phase transition in swollen gels
29. Temperature dependences of swelling and mechanical behaviour of poly(N-vinylcaprolactam-co-1-vinyl-2-pyrrolidone) gels in water |
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Authors: | M Ilavský G Mamytbekov Z Sedláková L Hanyková K Dušek |
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Affiliation: | (1) Faculty of Mathematics and Physics, Charles University, 180 00 Prague 8, Czech Republic, XX;(2) Institute of Macromolecular Chemistry, Academy of Sciences of Czech Republic, 162 06 Prague 6, Czech Republic, XX |
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Abstract: | Summary
Ionized networks of statistical copolymers of N-vinylcaprolactam (VCL), 1-vinyl-2-pyrrolidone (VP) (mole ratios of VCL/VP = 1/0, 0.9/0.1, 0.8/0.2, 0.7/0.3 and 0.5/0.5),
an ionic comonomer, N,N-diallyl-(N,N-dimethyl)ammonium chloride (mole fractions 0, 0.005, 0.01 and 0.02) and a crosslinker, 1,1'-divinyl-3,3'-(ethane-1,1-diyl)di(2-pyrrolidone)
(mole fractions 0.016, 0.024, 0.032 and 0.048) were prepared by radiation polymerization in water/ethanol mixture (H2O/EtOH = 0.5/0.5 by vol). Their swelling and mechanical behaviour was investigated in water at various temperatures. For all
copolymers, a continuous transition was found from the expanded (at low temperatures) to collapsed (at high temperatures)
state; the transition temperature T
tr increases with increasing contents of VP and the ammonium salt in gels. The shift of T
tr to higher temperatures is caused by hydrophilicity of network chains increasing with increasing VP contents. The decrease
in swelling with increasing temperature is accompanied by an increase in equilibrium modulus, so that mechanical behaviour
is predominantly determined by swelling.
Received: 31 October 2000/Revised version: 18 December 2000/Accepted: 18 December 2000 |
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