| Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu（Ⅲ）, β-diketones and 1,10-phenanthroline |
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| 引用本文： | 刘兴旺,;王娜,;索全伶.Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu（Ⅲ）, β-diketones and 1,10-phenanthroline[J].中国稀土学报(英文版),2008,26(6):778-782. |
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| 作者姓名： | 刘兴旺 ;王娜 ;索全伶 |
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| 作者单位： | [1]School of Chemical Engineering Inner Mongolia University of Technology, Hohhot 010051, China;; [2]Baotou Teacher＇s College, Baotou 014030, China |
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| 基金项目： | Project supported by the Natural Science Foundation of Inner Mongolia （200508010210）, the Education Department of Inner Mongolia （NJ06002, NJcxy08124） and Science and Technology Bureau of Baotou （2007G1013） Acknowledgment： One of the author Liu Xingwang is very grateful to John A. Elix in Department of Chemistry, Australian National University for his kind help. |
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| 摘 要： | Three novel β-diketones （HPPP, HTPP, and HFPP） ligands were synthesized by Sonogashira coupling reaction and Claisen condensation. The structure of β-diketones was confirmed with elemental analysis, IR, NMR and MS spectra. Three new ternary complexes consisting of Eu（Ⅲ）, β-diketones, and 1,10-phenanthroline（phen） were synthesized and characterized as TbL3phen （L=PPP, TPP, FPP） with elemental analysis, chemical analysis, and IR spectra, and their luminescence properties were studied.
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| 关 键 词： | β二酮 三重复合 发光性质 稀土 |
| 收稿时间： | 8 April 2007 |
Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(III), β-diketones and 1,10-phenanthroline |
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| Xingwang LIU, Na WANG,Quanling SUO.Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(III), β-diketones and 1,10-phenanthroline[J].Journal of Rare Earths,2008,26(6):778-782. |
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| Authors: | Xingwang LIU Na WANG Quanling SUO |
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| Affiliation: | aSchool of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China;bBaotou Teacher's College, Baotou 014030, China |
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| Abstract: | Three novel β-diketones (HPPP, HTPP, and HFPP) ligands were synthesized by Sonogashira coupling reaction and Claisen condensation. The structure of β-diketones was confirmed with elemental analysis, IR, NMR and MS spectra. Three new ternary complexes consisting of Eu(III), β-diketones, and 1,10-phenanthroline(phen) were synthesized and characterized as TbL3phen (L=PPP, TPP, FPP) with elemental analysis, chemical analysis, and IR spectra, and their luminescence properties were studied. |
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| Keywords: | β -diketone ternary complex luminescence property rare earths |
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