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低温固化静电植绒胶的研制
引用本文:车广波,刘宏,刘春波,崔运成,李传碧. 低温固化静电植绒胶的研制[J]. 中国胶粘剂, 2005, 14(3): 18-21
作者姓名:车广波  刘宏  刘春波  崔运成  李传碧
作者单位:1. 吉林师范大学化学学院,吉林省,四平市,136000
2. 吉林师范大学信息技术学院,吉林省,四平市,136000
基金项目:吉林省科学技术厅资助项目(980547)四平市科学技术局资助项目(970156)
摘    要:以丙烯酸系单体和环氧树脂为原料、OP和十二烷基硫酸钠为乳化剂、K2S2O8为引发剂、N-羟甲基丙烯酰胺(NMA)和甲基丙烯酸为交联剂,采用乳液聚合,在(82±1)℃和变速搅拌下,合成了自交联型可低温固化的静电植绒胶。应用该胶静电植绒时,在80℃的烘干条件下,仅需5min即可固化。由该胶所制得的植绒产品干磨4000次不见底;湿磨1300次不见底;柔软度3.8cm。

关 键 词:低温  固化  静电植绒胶  环氧树脂  (甲基)丙烯酸及其酯
文章编号:1004-2849(2005)03-0018-04
修稿时间:2004-03-15

Preparation of electrostatic flocking adhesive of solidification in low temperature
CHE Guang-bo,LIU Hong,LIU Chun-bo,CUI Yun-cheng,LI Chuan-bi. Preparation of electrostatic flocking adhesive of solidification in low temperature[J]. China Adhesives, 2005, 14(3): 18-21
Authors:CHE Guang-bo  LIU Hong  LIU Chun-bo  CUI Yun-cheng  LI Chuan-bi
Abstract:The experiment is conducted by using monomer mixture of the series of acrylate and epoxy resin as raw materials, OP and sodium lauryl sulfate as emulsifiers, potassium persulphate as initiator, N-hydroxymethylacrylamide and methylacrylic acid as cross-linking agent. It utilizes the method of emulsion polymerization to synthesize electrostatic flocking adhesive of self-crosslinking and low-temperature solidification for the first time under the condition of 82±1℃ and speed-change stirring. When this kind of adhesive is used to flock electrostatically,it can be solidified only in five minutes in the stoving temperature of 80℃. The background of its flocking products is invisible by dry-grinding for 4000 times and wet-grinding for 1300 times. The soft degree of its product is 3.8cm.
Keywords:low temperature  solidification  electrostatic flocking adhesive  epoxy resin  (methyl) acrylic acid and ester
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