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Study on the transferability of the time temperature superposition principle to emulsions
Authors:Muehlbach M  Brummer R  Eggers R
Affiliation:Department of Rheology/Thermal Analysis, Beiersdorf AG, PO Box 538, Unnastrasse 48, 20253 Hamburg, Germany;and Process Engineering II (Heat and Materials Transport), Technical University Hamburg-Harburg, Eissendorfer Strasse 38, 21071 Hamburg, Germany
Abstract:The instability of emulsions is basically clarified by a phase separation. The separated phase can either cream or sediment. Destabilization is mostly compounded by coalescence and gives a first indication through extension of droplets. In the cosmetics industry as well as many other branches of industry such as the food industry and paint and coatings industry, product stability is one of the most important quality criteria. Many stability tests have already been performed with the widest variety of methods from different fields of technology. In research and development it is especially important to obtain quick results on the stability of a formulation. Such results represent a tool that can help developers find an optimal formulation in a short time. In addition, they can shorten development times, leading to quicker introduction of a product in the market. Moreover, they can help to reduce storage stability tests to minimum, making less climatized rooms, space and work required to predict shelf-lives. The cycle test is an example of such a method developed in the field of rheology [1]. In this test the sample is subjected to continuously changing temperatures and its behavior observed. However, other methods can also conceivably used to predict stabilities. The aim of this work is to find a new model to predict the long-term stability. This model should be based on empirical data and it should determine the applicability of the time temperature superposition (TTS) principle to emulsions.
Keywords:rheology    stability of emulsions    time temperature superposition principle
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