| 聚丙烯接枝物反应挤出增容PP/PA6共混物的形态结构 |
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| 引用本文： | 李笃信,贾德民,郭宝春.聚丙烯接枝物反应挤出增容PP/PA6共混物的形态结构[J].高分子材料科学与工程,2002,18(1):71-74. |
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| 作者姓名： | 李笃信 贾德民 郭宝春 |
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| 作者单位： | 1. 华南理工大学高分子系,广东,广州,510641;湘潭大学高分子系,湖南,湘潭,411105
2. 华南理工大学高分子系,广东,广州,510641 |
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| 基金项目： | 广东省自然科学基金资助项目 (95 0 2 6 6 ) |
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| 摘 要： | 采有PP熔融接枝MAH和不饱和羧酸混合单体通过反应挤出增容PP/PA6共混物，研究了增容共混物的形态结构。SEM、TEM观察表明，接枝物能明显降低共混物的分散相尺寸，改善体系的分散状况，提高共混物两相的相容性；增容共混物的两相界面结合改善，相界面变得模糊。WAXD、DSC测试表明，用该接枝物增容后的共混物，组分的Xc下降，分散相微晶尺才减小。研究结果表明该接枝物是PP/PA6共混体系的有效增容剂。
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| 关 键 词： | 聚丙烯／尼龙6共混物 接枝物 形态结构 |
| 文章编号： | 1000-7555(2002)01-0071-04 |
| 修稿时间： | 2000年4月29日 |
STUDY ON THE MORPHOLOGY OF COMPATIBILIZED PP/PA6 BLEND BY PP GRAFT |
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| LI Du xin ,JIA De min ,GUO Bao chun.STUDY ON THE MORPHOLOGY OF COMPATIBILIZED PP/PA6 BLEND BY PP GRAFT[J].Polymer Materials Science & Engineering,2002,18(1):71-74. |
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| Authors: | LI Du xin JIA De min GUO Bao chun |
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| Affiliation: | LI Du xin 1,2,JIA De min 1,GUO Bao chun 1 |
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| Abstract: | Tbe compatibilization of the melt graft of PP with MAH and unsaturated acid on PP/PA6 blend by reactive extrusion was studied in this paper. The results showed that the graft can improve the compatibility of PP/PA6 blend efficiently. SEM and TEM results indicate that the homogeneity of compatibilized PP/PA6 blend has improvement and the particle size of dispersed phase has significant reduction, and the interface become more indistinct. The results of WAXD and DSC show that X c of compatibilized PP/PA6 blend has decreased and the microcrystal size of dispersed phase has also decreased. |
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| Keywords: | PP/PA6 blend graft copolymer morphology |
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