| 硅酸薄荷酯的合成研究 |
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| 引用本文： | 任建新,穆晓丽,罗嘉,藏阳陵,邱德跃.硅酸薄荷酯的合成研究[J].精细化工中间体,2010,40(1):37-39. |
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| 作者姓名： | 任建新 穆晓丽 罗嘉 藏阳陵 邱德跃 |
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| 作者单位： | 1. 湖南中烟公司,湖南,长沙,410014
2. 湖南化工研究院,国家农药创制工程技术研究中心,湖南,长沙4100140 |
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| 摘 要： | 以硅酸乙酯和薄荷醇为原料,在碱性催化剂作用下合成了硅酸薄荷二酯;以四氯化硅和薄荷醇为原料,三乙胺为缚酸剂合成了硅酸薄荷三酯。用1HNMR和GC-MS对合成的产物进行了结构表征。
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| 关 键 词： | 薄荷醇 硅酸酯 酯化反应 |
Synthesis of Menthol Orthosilicate |
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| REN Jian-xin,MU Xiao-li,LUO Jia,ZANG Yang-ling,QIU De-yue.Synthesis of Menthol Orthosilicate[J].Fine Chemical Intermediates,2010,40(1):37-39. |
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| Authors: | REN Jian-xin MU Xiao-li LUO Jia ZANG Yang-ling QIU De-yue |
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| Affiliation: | 1.China Tobacco Hunan Industrial Co.,Ltd, Changsha 410014, China; 2.National Engi Center for Agrochemicals, Hunan Research Institute of Chemical Industry, Changsha 410007, neering Research China) |
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| Abstract: | Dimenthoxydiethoxysilanes were synthesized by the ester exchange reaction between tetraethyl silicate and menthol in the presence of base catalyst. In addition, trialoxysilanols was synthesized by reaction of SICl4 with menthol using Et3N as the acid binding agent. The title compunds were confirmed by 1H NMR and GC-MS spectra. |
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| Keywords: | menthol menthol orthosilicate esterification |
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