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锐钛矿TiO_2的水热法制备以及紫外光降解甲醛
引用本文:张一兵,汪建,江雷. 锐钛矿TiO_2的水热法制备以及紫外光降解甲醛[J]. 电子元件与材料, 2009, 28(5). DOI: 10.3969/j.issn.1001-2028.2009.05.007
作者姓名:张一兵  汪建  江雷
作者单位:1. 上饶师范学院,化学系,江西,上饶,334001;国家纳米科学中心,北京,100080
2. 上饶师范学院,化学系,江西,上饶,334001
3. 国家纳米科学中心,北京,100080;中国科学院化学研究所,北京,100080
基金项目:国家重点基础研究发展规划(973计划),国家高技术研究发展计划(863计划),江西省教育厅科技项目 
摘    要:用硫酸钛水热法制备了纳米TiO2光催化剂,研究了纳米TiO2的形态结构特征及其光催化性能,并探讨了甲醛溶液的初始pH值和初始浓度、TiO2用量、降解温度和时间对光催化降解反应的影响。结果表明,制备的锐钛矿TiO2产物平整而密实,它由八面体结构的TiO2纳米晶大面积自组装而成。在35℃降解温度下采用254nm紫外光源照射1h后,锐钛矿TiO2对甲醛的降解率达到51.10%,2h后达68.42%。

关 键 词:无机非金属材料  水热法  锐钛矿TiO2  光降解  催化  甲醛

Anatase TiO_2 prepared by hydrothermal method and its photodegradation on formaldehyde under UV
ZHANG Yibing,WANG Jian,JIANG Lei. Anatase TiO_2 prepared by hydrothermal method and its photodegradation on formaldehyde under UV[J]. Electronic Components & Materials, 2009, 28(5). DOI: 10.3969/j.issn.1001-2028.2009.05.007
Authors:ZHANG Yibing  WANG Jian  JIANG Lei
Affiliation:1. Department of Chemistry;Shangrao Normal University;Shangrao 334001;Jiangxi Province;China;2. National Center for Nanoscience and Nanotechnology;Beijing 100080;3. Institute of Chemistry;Chinese Academy of Sciences;China
Abstract:TiO2 nanocrystalline photocatalyst was prepared by hydrothermal method with titanium sulfate as raw material. The microstructure, morphology and photocatalytic activities of as-prepared anatase TiO2 were studied. And the effects of initial pH value and concentration of formaldehyde solution, TiO2-used amount, degradation temperature and time on the photodegradation of anatase TiO2 were also discussed. The results show that anatase TiO2 product is flat and densely packed in large area. The product is made up...
Keywords:non-metallic inorganic material  hydrothermal method  anatase TiO2  photodegradation  catalysis  formaldehyde  
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