| 聚辛二酸木糖醇酯生物弹性体的制备与性能研究 |
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| 引用本文： | 吴畏,东为富,李婷,陈明清,梅涛锋,林玲.聚辛二酸木糖醇酯生物弹性体的制备与性能研究[J].化工新型材料,2012,40(8):52-54. |
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| 作者姓名： | 吴畏 东为富 李婷 陈明清 梅涛锋 林玲 |
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| 作者单位： | 江南大学化学与材料工程学院,无锡,214122 |
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| 基金项目： | 国家自然基金项目，中央高校自主科研项目资助 |
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| 摘 要： | 以辛二酸和木糖醇为单体,通过熔融缩聚反应,得到一种网络型聚酯生物弹性体(PXO),并对其结构进行表征。研究表明,通过单体摩尔配比和反应条件的控制,材料具有可调的力学性能(拉伸强度0.16～1.72MPa、伸长率166%～212%),亲水性能(水接触角65°～81°)和吸水率(2%～16%);XRD和DSC分析表明,材料在室温下为无定形态和结晶态共存的微相分离结构,且材料的玻璃化转变温度都低于室温,是一种性能优异的生物弹性体。
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| 关 键 词： | 弹性体 木糖醇 辛二酸 |
Preparation and property of poly(xylitol suberic)bioelastomer |
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| Wu Wei
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Dong Weifu
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Li Ting
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Chen Mingqin
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Mei Taofeng
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Lin Ling.Preparation and property of poly(xylitol suberic)bioelastomer[J].New Chemical Materials,2012,40(8):52-54. |
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| Authors: | Wu Wei Dong Weifu Li Ting Chen Mingqin Mei Taofeng Lin Ling |
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| Affiliation: | Wu Wei Dong Weifu Li Ting Chen Mingqin Mei Taofeng Lin Ling(School of Chemical and Material Engineenring,Jiangnan University,Wuxi 214122) |
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| Abstract: | A novel kind of bioelastomer was successfully prepared by melt polycondensation of xylitol and suberic acid(PXO bioelastomer).It was revealed that the mechanical properties can be adjusted(tensile strength,0.16~1.72MPa;elongation at break,166%~212%)by changing the dosage of suberic acid and crosslinking time,and it was easy to get hydrophilicity with water contact angle between 58oand 78°,and water-uptake between 1.77% and 25.82%.XRD and DSC spectra inidcated that there was a micro-phase separation structure originating from crystalline and amorphous regions in it.The glass transition temperatures were blow room temperature,which suggested that PXO was a good kind of elastomer. |
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| Keywords: | elastomer xylitol suberic acid |
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