| 酸量的调变对烷基转移催化剂性能的影响 |
| |
| 引用本文： | 赵胤,邓广金,李正,刘春艳,李树丰,孙建刚,侯立波. 酸量的调变对烷基转移催化剂性能的影响[J]. 化工科技, 2012, 20(4): 31-33 |
| |
| 作者姓名： | 赵胤 邓广金 李正 刘春艳 李树丰 孙建刚 侯立波 |
| |
| 作者单位： | 中国石油吉林石化公司研究院,吉林 吉林,132021 |
| |
| 摘 要： | 用小型固定床反应器进行多异丙苯与苯烷基转移催化反应研究,通过改变催化剂载体拟薄水铝石(SB粉)加入量调变其酸量,并进行NH3-TPD和活性评价,结果表明:质量分数10%的SB粉HMCM-49/Hβ分子筛催化剂用于多异丙苯与苯烷基转移较为适宜。在180℃,总液空速为1.4～1.6h-1条件下,二异丙苯转化率达到60%以上,三异丙苯转化率达到50%以上。
|
| 关 键 词： | HMCM-49/Hβ分子筛 烷基转移 SB粉 |
Effects of modification of acid amount on the performance of transalkylation catalyst |
| |
| ZHAO Yin , DENG Guang-jin , LI Zheng , LIU Chun-yan , LI Shu-feng , SUN Jian-gang , HOU Li-bo. Effects of modification of acid amount on the performance of transalkylation catalyst[J]. Science & Technology In Chemical Industry, 2012, 20(4): 31-33 |
| |
| Authors: | ZHAO Yin DENG Guang-jin LI Zheng LIU Chun-yan LI Shu-feng SUN Jian-gang HOU Li-bo |
| |
| Affiliation: | (Research Institute of Jilin Petrochemical Co. Ltd. ,PetroChina,J ilin 132021,China) |
| |
| Abstract: | The effects of the modification of acid amount on the transalkylation reaction from multiisopropylbenzene and benzene were studied by using a fixed-bed reactor. The catalysts were characterized by NH3-TPD and activity evaluation experiments. The results showed that the feasible addition amount of SB powder for the transalkylation reaction was 10%. The effects of temperature and feeding velocity on the preferred HMCM-49/Hβmolecular sieve with addition of 10% SB powder for the multiisopropylbenzene reaction were investigated. It was showed that the conversion of diisopropylbenzene and triisopropylbenzene was 65.2% and 55.6%, respectively, at 180 ℃ and total liquid hourly spacevelocity of 1.4 ～1.6 h^-1. |
| |
| Keywords: | HMCM-49/Hβ Molecular sieve Transalkylation SB Powder |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
