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Easy preparation of carbon sheets with controlled microstructures from sucrose/layered superabsorbent polymer hydrogels
Authors:Haiwang Wang  Tianbo Zhao  Xinfang Wei  Huaihe Song  Fengyan Li  Xin Xu  Jian Qi  Ce Miao  Shuai Zhang  Man Zhang  Qing Chen  Yin Lin
Affiliation:aKey Laboratory of Cluster Science of Ministry of Education, Beijing Institute of Technology, Beijing 100081, PR China;bState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China;cDepartment of Applied Chemistry, Beijing Institute of Petrochemical Technology, Beijing 102617, PR China;dDepartment of Chemistry, Chifeng University, Chifeng 024000, PR China
Abstract:An easy method is described for fabricating carbon sheets with nanostructures using sucrose as a carbon precursor and a layered superabsorbent polymer (LSAP) as a structure-directing agent. The method is based on the interaction of the three-dimensional polymer networks of the LSAP with a sucrose solution in the hydrogel cells. The synthesis scheme consists of: (a) preparation of the LSAP, (b) preparation of layered hydrogels by immersing the LSAP in the sucrose solution for 2 days, (c) carbonization of the layered hydrogels containing the sucrose solution. The synthesized carbon sheets show different microstructures including petal-like, regular and interleaved types, which can be controlled by simply adjusting the initial concentration of the sucrose solution in the hydrogel cells. Moreover, a formation mechanism for the carbon sheets is proposed.
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