木屑与煤慢速共热解产物特性研究

采用TG-FTIR联用的分析方法对木屑与煤共热解产物进行分析,结果发现,木屑与煤共热解产物不是两者单独热解的简单叠加,而是木屑与煤协同反应相互促进或抑制的结果。煤化程度越高木屑与煤共热解过程中CO和CH₄的产率越多,CO₂的产率越少,液体和固体产物越多。木屑与煤掺混比例对于共热解产物的影响规律性不是非常明显,对于CO和CH₄,掺混比例5:5时产率最低;CO₂在共热解温度<500 ℃时,掺混比例5:5时产率最高,而在共热解温度>500 ℃时,随着煤的掺混比例的增加产率逐渐减小。木屑与褐煤的共热解固体产率随着掺混比例的增加逐渐增大,木屑与无烟煤的共热解固体产率正好相反。

Characteristics of Sawdust and Coal Slow Co-pyrolysis Products

By using TG-FTIR method,the co-pyrolysis products of sawdust and coal were analyzed.It was found that co-pyrolysis products yield was not simple accumulation of mono-pyrolysis,but the result of inhibition or acceleration effect of synergistic reaction.With the increase of coal rank,the CO and CH₄ products yields increased,CO₂ product yield decreased,and liquid and solid products yields increased.The mixture ratio had less influence on the co-pyrolysis products.With the mixture ratio of 5:5,the CO and CH₄ yields were the minimum.When the co-pyrolysis temperature was less than 500 ℃,CO₂ yield was the maximum in mixture ratio of 5:5.While the co-pyrolysis temperature was over 500 ℃,CO₂ yields decreased with the increase of mixture ration.Solid product yields of sawdust and lignite co-pyrolysis gradually increased as the sawdust ratio in blending raw material promoted.But solid product yields of sawdust and anthracite co-pyrolysis were going in the opposite direction.