Environmental photostability of SF(6)-etched silicon nanocrystals |
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Authors: | R W Liptak J Yang N J Kramer U Kortshagen S A Campbell |
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Affiliation: | Department of Electrical and Computer Engineering, University of Minnesota, Minneapolis, MN?55455, USA. |
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Abstract: | We report on the long-term environmental stability of the photoluminescent (PL) properties of silicon nanocrystals (SiNCs). We prepared sulfur hexafluoride (SF(6)) etched SiNCs in a two-stage plasma reactor and investigated their PL stability against UV irradiation in air. Unlike SiNCs with hydrogen-passivated surfaces, the SF(6)-etched SiNCs exhibit no photobleaching upon extended UV irradiation despite surface oxidation. Furthermore, the PL quantum yield also remains stable upon heating the SF(6)-etched SiNCs up to 160?°C. The observed thermal and UV stability of SF(6)-etched SiNCs combined with their PL quantum yields of up to ~50% make them attractive candidates for UV downshifting to enhance the efficiency of solar cells. Electron paramagnetic spin resonance indicates that the SF(6)-etched SiNCs have a lowered density of defect states, both as-formed and after room temperature oxidation in air. |
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