Investigation of nitrate salts for solar latent heat storage

Solar thermal applications require some means of thermal energy storage. Amongst several storage concepts, latent heat storage is quite suitable because of its high storage density and almost constant temperature during charging and discharging. The temperature range between 200 and 300°C is considered to be important for solar total energy systems. In this temperature range, sodium nitrate and its mixed salts with other nitrates including eutectic and off-eutectic salts are candidates.

The present paper deals with heat transfer in a latent heat storage unit utilizing these salts. A method of rough estimation of the thermal conductivity of the storage materials is described, and the temperature history of the storage material experimentally obtained is compared with numerical solutions and found to be in reasonably good agreement.

It is seen that the temperature of the heat transfer surface quickly drops soon after the appearance of a solid phase due to low thermal conductivity of these salts. Ways to avoid this temperature drop are discussed.