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Synthesis of Cellulose-Based Macromolecular Coupling Agent and its Utilization in Poly (butylene succinate)/Wood Flour Composites
Authors:Xiaopeng Yue  Yongjian Xu  Nina Gou  Hongkui Li
Affiliation:1. Shaanxi Province Key Laboratory of Papermaking Technology and Specialty Paper, Shaanxi University of Science and Technology, Xi’an, China;2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, China;3. Shaanxi Institute of Zoology, Xi’an Branch of Chinese Academy of Sciences, Xi’an, China
Abstract:A long fatty side chain was introduced into the macromolecule of hydroxyethyl cellulose (HEC) via esterification reaction. The hydrophobicity of hydroxyethyl cellulose lauric acid ester (HECLAE) was enhanced in comparison with HEC. The obtained HECLAE was used as macromolecular coupling agent in poly (butylene succinate)/wood flour composites and exhibited a positive influence on improving the mechanical performance of composites. Besides, HECLAE plays a role as a hydrophobic agent in composites. A significant increase in storage modulus (E’) was observed upon the incorporation of treated wood flour. SEM images showed that the dispersion of treated wood flour in PBS matrix was improved.
Keywords:Cellulose ester  Composites  Hydroxyethyl cellulose  Macromolecular coupling agent  Poly (butylene succinate)  Wood flour
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