Investigation of kinetic recovery process in low dose neutron-irradiated nuclear graphite by thermal annealing |
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Authors: | Yuhao Jin Katsumi Yoshida Desheng Ai Tadashi Maruyama |
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Affiliation: | 1. State Key Lab of New Ceramic and Fine Processing, Key Laboratory of Advanced Materials (MOE), School of Materials Science &2. Engineering, Tsinghua University, Beijing, China;3. Laboratory for Advanced Nuclear Energy, Institute of Innovative Research, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan;4. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, China;5. Laboratory for Advanced Nuclear Energy, Institute of Innovative Research, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan;6. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, China |
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Abstract: | To investigate the kinetic recovery process of low dose neutron-irradiated graphite, nuclear-grade isotropic graphite IG-110U and ETP-10 were neutron irradiated using the JMTR up to 1.38 × 1023 n/m2 (En > 1 MeV) at ~473 K. In-situ measurement of macroscopic length was conducted during the isothermal and isochronal annealing process from room temperature up to 1673 K. From room temperature to 773 K for IG-110U, and to 1023 K for ETP-10, macroscopic lengths, lattice parameters, and unit cell volumes of both specimens recovered to their pre-irradiation values, and this recovery process subdivided into two stages. The activation energies of macroscopic volume recovery at 523–673 K and 673–773 K were determined to be ~0.22 eV and ~0.57 eV for IG-110U, respectively; ~0.13 eV and ~2.59 eV at 523–923 K and 923–1023 K for ETP-10, respectively. The migration of not only single interstitials but also interstitials dissociated from submicroscopic interstitial groups along basal planes followed by vacancy-interstitial recombination play a dominant role in the first stage. The second stage is suggested to proceed via the motion of carbon groups along basal planes for IG-110U, and migration of single interstitials along the c-axis for ETP-10. During 773 K or 1023 K up to 1673 K, macroscopic length continuously shrank with decreasing shrinking rate, even with a turnaround to swell at 1173 K for IG-110U. |
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Keywords: | Nuclear graphite low-dose neutron irradiation kinetic recovery process macroscopic dimension lattice parameter activation energy |
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