Photocatalytic degradation of oxytetracycline using TiO2 under natural and simulated solar radiation |
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Authors: | Joã o H.O.S. Pereira,Ví tor J.P. Vilar,Maria T. Borges,Oscar Gonzá lez,Santiago Esplugas,Rui A.R. Boaventura |
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Affiliation: | aLSRE-Laboratory of Separation and Reaction Engineering, Departamento de Engenharia Química, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal;bCIMAR Centre for Marine and Environmental Research, Departmento de Biologia, Faculdade de Ciências da Universidade do Porto, Rua Campo Alegre, 4169-007 Porto, Portugal;cFacultat de Química, Departament d’Enginyeria Química, Universitat de Barcelona, Martí i Franquès 1, 08028 Barcelona, Spain |
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Abstract: | The main objective of the present study was to assess the photocatalytic degradation over TiO2 of an aqueous solution containing 20 mg L−1 of the antibiotic Oxytetracycline (OTC) using simulated solar radiation, seconded by a solar radiation experiment carried out in a pilot plant equipped with Compound Parabolic Collectors (CPCs) under the optimal conditions found in preliminary lab-scale experiments. These comprehended a set of 1 L aqueous experiments with TiO2 loads ranging from 0.1 to 0.5 g L−1 starting from different initial pH values. These experiments were carried out in a Solarbox equipped with a 1000 W Xe-OP lamp. OTC degradation was followed by HPLC-DAD, while its mineralization was followed by the removal of Total Organic Carbon.Results suggested that 0.5 g L−1 of TiO2 with no initial pH adjustment (pH ∼ 4.4) was the best combination for the removal of both OTC (100% after 40 min of irradiation; 7.5 kJ L−1 of UV dose) and TOC (>90% after 180 min of irradiation; 38.3 kJ L−1 of UV dose). Under these conditions, the BOD5/COD ratio rose from almost 0 to nearly 0.5, showing a remarkable improvement in biodegradability, while inhibition percentage of bioluminescence of Vibrio fischeri after 15 min of exposition measured by Microtox® decreased significantly from 35% down to 7%. A scheme of the OTC degradation pathway is proposed, based on the results obtained from this particular experiment.The solar photocatalytic experiment done under the same conditions was carried out in a solar pilot plant equipped with CPCs. OTC and TOC removal was followed as a function of accumulated UV energy entering the reactor. Results showed a 100% OTC and almost 80% TOC removal with 1.8 kJ L−1 and 11.3 kJ L−1 of photo treatment energy, respectively. |
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Keywords: | Heterogeneous photocatalysis Antibiotics Solar radiation Compound Parabolic Collectors (CPCs) |
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