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Mineral saturated hydrocarbons and mineral aromatic hydrocarbons in tropical plant oils and their removal by molecular distillation
Authors:Mingming Zhang  Hai Zhang  Tosin Michael Olajide  Wenming Cao  Yan Wang  Hong Zhang  Yuanrong Jiang
Affiliation:Analytical Center, Wilmar (Shanghai) Biotechnology R&D Center Co., Ltd, Shanghai, China
Abstract:Nowadays, tropical plant oils (e.g., palm oil and coconut oil) are extensively used in consumer products, especially in infant formulas. However, there is a lack of statistical data on the levels of mineral oil in these oils, including mineral saturated hydrocarbons (MOSH) and mineral aromatic hydrocarbons (MOAH). In this study, we reported a survey of MOSH/MOAH in tropical oils, and in addition, we provided an effective strategy (i.e., molecular distillation) to reduce their contents. A total of 686 tropical plant oils were collected from five tropical countries for this survey. The highest quantifiable MOSH and MOAH concentrations were up to 456.0 and 78.9 mg kg−1, respectively. Interestingly, MOSH was ubiquitous in almost all the tested samples. The distribution of sub-fractions for MOSH centered at C25–C35 and C35–C40 in most crude and refined oils. After distillation, the MOH sub-fraction ≤40 was effectively removed, but >40 was unaltered.
Keywords:coconut oil  mineral oil  molecular distillation  online LC-GC-FID  palm kernel oil  palm oil  palm olein
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