A Lean-Zinc and Zincophilic Anode for Highly Reversible Zinc Metal Batteries |
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Authors: | Chao Li Qingguo Shao Kan Luo Yiqiu Gao Wenwen Zhao Ning Cao Shiyu Du Xin Jin Peichao Zou Xiaobei Zang |
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Affiliation: | 1. School of Materials Science and Engineering, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, 266580 P. R. China;2. Centre for the Physics of Materials and Department of Physics, McGill University, Montreal, Quebec, H3A 2T8 Canada;3. State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580 P. R. China;4. Department of Physics and Astronomy, University of California, Irvine, CA, 92697 USA |
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Abstract: | Lean-zinc anode is a promising configuration that can eliminate the trade-off of energy density and cycle lifetime of zinc metal (Zn0) batteries. However, there are rare investigations of lean-Zn anode designs and it remains a grand change to sustain high zinc reversibility under lean zinc conditions. Herein, a lean-Zn anode design based on a hierarchical and zincophilic cobalt metal (Co0) nanowire-decorated carbon host, which is derived from a ZnCo bimetallic organic framework, is reported. Within the lean-Zn anode, the trace amount of Zn0 acts as a zinc reservoir to make up for any irreversible loss of zinc source upon cycling, while the zincophilic Co0 nanowires can guide uniform zinc nucleation and growth through a lattice matching mechanism. Consequently, high Zn0 reversibility (average Coulomb efficiency of 99.6% for 4250 cycles), low nucleation overpotential (50.8 mV at 1 mA cm−2), and uniform and compact zinc electrodeposition are realized. When coupling the lean-Zn anode with a Zn-containing cathode, the full cell delivers high Coulomb efficiency (99.6% for 4250 cycles on average) and a long lifetime of more than 5000 cycles. |
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Keywords: | Coulomb efficiency lattice matching lean-Zn anodes ZnCo ZIF-L derived carbon |
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