Fabrication and performance of PEN SOFCs with proton-conducting electrolyte |
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Authors: | Zhong Li Luo Jingli and Karl Chuang |
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Affiliation: | (1) College of Chemical and Energy Engineering, South China University of Technology, Guangzhou, 510640, China;(2) Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB, T6G 2G6, Canada |
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Abstract: | A positive-electrolyte-negative (PEN) assembly solid oxide fuel cell (SOFC) with a thin electrolyte film for intermediate
temperature operation was fabricated. Instead of the traditional screen-printing method, both anode and cathode catalysts
were pressed simultaneously and formed with the fabrication of nano-composite electrolyte by press method. This design offered
some advantageous configurations that diminished ohmic resistance between electrolyte and electrodes. It also increased the
proton-conducting rate and improved the performance of SOFCs due to the reduction of membrane thickness and good contact between
electrolyte and electrodes. The fabricated PEN cell generated electricity between 600°C and 680°C using H2S as fuel feed and air as oxidant. Maximum power densities 40 mW·cm−2 and 130 mW·cm−2 for the PEN configuration with a Mo-Ni-S-based composite anode, nano-composite electrolyte (Li2SO4+Al2O3) film and a NiO-based composite cathode were achieved at 600°C and 680°C, respectively. |
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Keywords: | solid oxide fuel cells positive-electrolyte-negative assembly hydrogen sulfide |
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