Atomic-scale microstructure and elastic properties of quaternary Zr–Al–Si–C ceramics |
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Authors: | ZJ Lin LF He JY Wang MS Li YW Bao YC Zhou |
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Affiliation: | aShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China bGraduate School of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract: | Transmission electron microscopy characterizations and elastic properties of two quaternary carbides, i.e. Zr2(Al(Si))4C5 and Zr3(Al(Si))4C6 are reported. The space group and atomic-scale microstructures of both compounds were determined using a combination of selected area electron diffraction, convergent beam electron diffraction, high-resolution transmission electron microscopy and Z-contrast scanning transmission electron microscopy. In addition, the combined experimental and theoretical studies on elastic properties for Zr2(Al(Si))4C5 are presented. A full set of second-order elastic constants, bulk modulus, shear modulus, and Young’s modulus were calculated using first-principles calculations. Both experimental and theoretical works demonstrated that quaternary Zr–Al–Si–C ceramics possess close elastic properties to ZrC. Furthermore, Zr2(Al(Si))4C5 retained a high Young’s modulus up to about 1580 °C, which can be attributed to its comparable activation energy of lattice drag process to that of ZrC. |
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Keywords: | Ceramics Hot-pressing Crystal structure TEM Elastic property |
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