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Enhanced photocatalytic activity of TiO2 by polydimethylsiloxane deposition and subsequent thermal treatment at 800 °C
Authors:Myung-Geun JeongHyun Ook Seo  Kwang-Dae KimYoung Dok Kim  Dong Chan Lim
Affiliation:
  • a Department of Chemistry, Sungkyunkwan University, Suwon, 440-746, Korea
  • b Materials Processing Division, Korea Institute of Materials Science, Changwon, 641-010, Korea
  • Abstract:A thin film of polydimethylsiloxane (PDMS) was coated on TiO2 nanoparticles (P-25, Dagussa), and surface structures of the thin films were analyzed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Furthermore, photocatalytic activity of PDMS-coated TiO2 samples with various annealing temperatures was determined using UV irradiation. We show that the 800 °C-annealed sample of PDMS-coated TiO2 showed a two-fold higher photocatalytic activity with respect to the bare TiO2. The enhanced photocatalytic activity was attributed to the greater hydrophilicity of the annealed PDMS coating.
    Keywords:Photocatalysis  Evaporation  polydimethylsiloxane  Titanium Dioxide  Powders  Hydrophilic Interaction  Methylene Blue
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