Thermal effects on fracture of biaxial-oriented poly(ethylene terephthalate) (BOPET) film

The effect of temperature on the fracture behaviour of biaxial-oriented poly(ethylene terephthalate) (BOPET) film was studied using the Essential Work of Fracture (EWF) approach. Fracture tests were performed over the temperature range +25 to +160 °C at the speed of 5 mm/min using double edge notched tension (DENT) specimens. The length of the specimens was either along the machine direction (MD) (0°), transverse direction (TD) (90°) or at 45° to either MD or TD. Ductile tearing of the ligament region was noted over the entire temperature range in all three directions. A linear relationship was found between the specific total work of fracture and the ligament length at all test temperatures. Values of the specific essential work of fracture (w _e) in the MD and TD were similar and smaller than in the 45° direction. Within temperature range 25–140 °C, w _e showed little variation if any with respect to temperature. As expected, the Specific Non-Essential Work of Fracture (βw _p) was temperature dependent. This parameter increased with increasing temperature and reached a maximum around the glass transition temperature of BOPET (T _g ≈ 80 °C). The values of the maxima are respectively 16.15, 20.38 and 17.8 MJm⁻³ for the 0°, 45° and 90°.