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绿色环保木材用胶黏剂的研究
引用本文:阎春绵,张忠厚,何领好,吴卫林. 绿色环保木材用胶黏剂的研究[J]. 化学与粘合, 2008, 30(5): 4-7
作者姓名:阎春绵  张忠厚  何领好  吴卫林
作者单位:郑州轻工业学院材料化工学院河南省表界面科学重点实验室
摘    要:以过硫酸铵为引发剂制备聚丙烯酰胺预聚体,以次氯酸钠为氧化剂对淀粉进行氧化处理,将两者经过缩合反应得到接枝淀粉胶黏剂的主剂,用氮丙啶进行交联,得到了木材用改性淀粉胶。当缩合温度为60℃、氧化剂量为35mL、丙烯酰胺为淀粉质量的7.5%、交联剂为3%和交联时间3h时制得的胶黏剂胶合强度达到5.30MPa,耐水时间达33h。对各阶段试样进行了红外光谱和x射线衍射分析。

关 键 词:淀粉  木材胶黏剂  接枝改性  丙烯酰胺  氮丙啶  环保  耐水

Research on Environment Friendly Adhesive for Wood
YAN Chun-mian,ZHANG Zhong-hou,HE Ling-hao,WU Wei-lin. Research on Environment Friendly Adhesive for Wood[J]. Chemistry and Adhesion, 2008, 30(5): 4-7
Authors:YAN Chun-mian  ZHANG Zhong-hou  HE Ling-hao  WU Wei-lin
Affiliation:YAN Chun - mian, ZHANG Zhong - hou, HE Ling - hao ,WU Wei - lin ( Henan Provincial Key Laboratory of Surface and Interface Science, College of Material and Chemical Engineering, Zhengzhou Institute of Light Industry, Zhengzhou 450002, China)
Abstract:Nontoxic adhesive for wood was prepared by condensation reaction of oxidated starch with low molecular weight polyacrylamide and then cross - linking by aziridine. Ammonium persulfate was the initiator for synthesizing polyacrylamide and sodium hypochlorite was oxidant for preparing oxidated starch. The bonding strength was 5.30 MPa and the water - resisting time was 33h when the condensation temperature was 60℃, the oxidant amount was 35ml, the acrylamide content was 7.5% of starch mass, the crosslinking agent was 3% and the crosslinking time was 3h. The adhesive sampies were analyzed by FTIR and XRD.
Keywords:Starch  wood adhesive  grafting modification  acrylamide  aziridine  environment friendly  water-resisting
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