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镨掺杂铁酸铋粉晶的结构和磁性研究
引用本文:张静,吴玉洁,游泳,等.镨掺杂铁酸铋粉晶的结构和磁性研究[J].广东化工,2014(7):49-50.
作者姓名:张静  吴玉洁  游泳  
作者单位:[1]北京理工大学珠海学院数理学院,广东珠海519088 [2]广州大学物理电子工程学院,广东广州510006
摘    要:Pr掺杂的BiFeO3粉晶是由溶胶凝胶方法制备的,掺杂浓度为0≤x≤0.5.分别用X光衍射和综合物性测量系统对Bi1-x Prx FeO3粉晶样品的结构和磁性进行了测量和分析。分析结果表明,Pr掺杂与其他稀土元素掺杂明显不同.随着Pr掺杂量的增加,母体BiFeO3的结构由菱形R3c相变为正交Pnma相的过程中,出现了稳定的PbZrO3型正交Pbam过渡相.另外,随着掺杂浓度的增大,Bi1-x Prx FeO3的磁性逐渐增强,剩余磁化强度Mr在相变边界处有最大值,并且在进入Pnma相后逐渐减小。

关 键 词:多铁材料  结构相变  磁化强度

Structure and Magnetization Research on Pr doped BiFeO3 Powders
Jing Zhang,Wu Yujie,You Yong,Hu Yij,Deng JianjieI,Zhang Guocai.Structure and Magnetization Research on Pr doped BiFeO3 Powders[J].Guangdong Chemical Industry,2014(7):49-50.
Authors:Jing Zhang  Wu Yujie  You Yong  Hu Yij  Deng JianjieI  Zhang Guocai
Affiliation:1 (1. School of Mathematics and Physics, Beijing Institute of Technology, Zhuhai 5190881 2. School of Physics and Electronic Engineering, Guangzhou University, Guangzhou 510006, China)
Abstract:We have successfully synthesized the single phase Bi1-xPrxFeO3 (0≤x≤0.5) powders by the modified sot-gel method, and studied by combing the x-ray diffraction and physical properties measurement system measurements. It differs from substitutions of other rare-earth ions, there is a stable transitional phase of PbZrO3-Iike Pbam existing between the R3c-Pnma phase transition with the increase of Pr doped concentration. The magnetization of Bi1-xPrxFeO3 samples increases gradually with increasing Pr substituted concentration x, however, an inverse behavior occurs after passing a maximum across the phase boundary.
Keywords:multiferroic material: structural transformation  magnetization
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