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Clustering of platinum atoms into nanoscale particle and network on NaY zeolite
Authors:Ryong Rayoo  Sung June Cho  Chanho Pak  JeongYong Lee
Affiliation:(1) Department of Chemistry and Center for Molecular Science, Korea Advanced Institute of Science and Technology, Taeduk Science Town, 305-701 Taejon, Korea;(2) Department of Electronic Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Taeduk Science Town, 305-701 Taejon, Korea
Abstract:Platinum has been supported on NaY zeolite by ion exchange of Pt(NH3)42+. Clustering of Pt atoms into a 1 nm cluster, and three-dimensional quantum-size wire (3 nm thick) network (greater than 100 nm) from reduction of the Pt species has been investigated by extended X-ray absorption fine structure transmission electron microscopy and xenon adsorption measurements.
Keywords:Pt cluster supported on zeolites  quantum-size Pt wire network  metal-support interaction  EXAFS  TEM
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