| 聚噻吩乙炔的合成及其导电性 |
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| 引用本文： | 刘承美,谢洪泉.聚噻吩乙炔的合成及其导电性[J].高分子材料科学与工程,1995,11(3):36-40. |
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| 作者姓名： | 刘承美 谢洪泉 |
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| 作者单位： | 武汉华中理工大学化学系 |
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| 摘 要： | 对在水和甲醇－水混合介质中合成的聚噻吩乙炔（ＰＴＶ）前聚物（ｐｒｅｃｕｒｓｏｒ ｐｏｌｙｍｅｒ）的结构和性能进行了研究。不同聚合介质条件对单体转化率及前聚物的产率有一定影响。不同取代侧基影响ＰＴＶ前聚物的溶解性和热处理性能。并对ＰＴＶ膜碘掺杂后的导电率进行了初步研究。
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| 关 键 词： | 噻吩 聚噻吩乙炔 前聚物 导电率 |
STUDY ON THE PROPERTIES OF THE PRECURSOR POLYMER OF POLY(2,5-THIENYLENE VINYLENE) |
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| Liu Chengmei,Xie Hongquan.STUDY ON THE PROPERTIES OF THE PRECURSOR POLYMER OF POLY(2,5-THIENYLENE VINYLENE)[J].Polymer Materials Science & Engineering,1995,11(3):36-40. |
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| Authors: | Liu Chengmei Xie Hongquan |
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| Abstract: | The structures and properties of the precursor polymer of poly(2,5-thienylene vinylene)(PTV) synthesized in water or in methanol-water mixture were studied.Different reaction medium affected the monomer conversion and the yield of the precursor polymer in some extent.The solubility and thermal-elimination property of the precursor polymer are effected by the pendent group.l2 doped PTV film had a room-temperature conductivity of about 50 S.cm-1. |
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| Keywords: | s:thiophene poly(2 5-thienylene vinylene) precursor polymer conductivity conductive polymer |
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