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Dehydrogenation of Cyclohexane Over Ni Based Catalysts Supported on Activated Carbon using Spray-pulsed Reactor and Enhancement in Activity by Addition of a Small Amount of Pt |
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| Authors: | Rajesh B Biniwale Nobuko Kariya Masaru Ichikawa |
| Affiliation: | (1) Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200433, P. R. China;(2) Department of Chemistry, Shanghai Normal University, Shanghai, 200234, P. R. China |
| Abstract: | The polycrystalline silver after pre-treated with oxygen at high temperature was found to show excellent activity and selectivity in the process of direct dehydrogenation of methanol to anhydrous formaldehyde and the active oxygen species for this reaction was observed and proposed as the active centeres with in situ Raman scattering. |
| Keywords: | polycrystalline silver in situ Raman spectroscopy dehydrogenation of methanol oxygen species formaldehyde |
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