Radical polymerization of vinyl monomers in the presence of carbon black initiated by 2,2'‐azobisisobutyronitrile and benzoyl peroxide in ionic liquid

The radical polymerization behavior of vinyl monomers, such as styrene, methyl methacrylate (MMA), and vinyl acetate (VAc), in the presence of carbon black initiated by benzoyl peroxide (BPO) and 2,2'‐azobisisobutyronitrile (AIBN) in ionic liquid (IL) was compared with those in toluene. 1‐Butyl‐3‐methylimidazolium hexafluorophosphate was used as IL. The radical polymerization of vinyl monomers initiated by BPO and AIBN in the presence of carbon black was remarkably retarded in toluene. On the contrary, the retardation of the polymerization by carbon black was considerably reduced in IL. During the radical polymerization in the presence of carbon black, a part of polymer formed was grafted onto carbon black surface based on the termination reaction of the growing polymer radicals with carbon black surface. The percentage of grafting and molecular weight of polymer in IL were much higher than those in toluene. This may be due to the fact that lifetime of the growing polymer radical is prolonged because of high viscosity of IL. Therefore, the growing polymer radicals with higher molecular weight were trapped by carbon black surface, because of stabilization of polymer radicals. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008