Abstract: | The microstructure, dielectric properties and chemical state of Ti element on BaTi4O9 (f)/(0. 64 BaTi4O9-0. 36BaPr2Ti4O12 ) composites sample surface were characterized by X-ray diffraction (XRD) ,Transmission electron microscopy (TEM), LCR meter method and X-ray photoelectron spectroscopy (XPS).The results show that the system is composed of BaTi4O9 and BaPr2Ti4O12 two phases. Pr ions are distributed inthe BaTi4O9 grains and the segregation of Pr ions was observed on the grain boundaries of BaTi4O9/BaTi4O9.The content of Ti3 + and Ti2+ decrease in the BPT system composites due to the addition of BaTi4O9 fibers,which improved the dielectric properties of the system. BPT10 sample with 10 % BaTi4O9 fibers, has the bestdielectric properties in the system, its εr =64,tan δ = 1×10-4(at 1 MHz) , and it may be a potential candi-date for microwave dielectric ceramics. |