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Improvement of the hardness and wear resistance of (TiC, TiN)/Ti-6Al-4V surface-alloyed materials fabricated by high-energy electron-beam irradiation
Authors:Jun Cheol Oh  Sunghak Lee  Mikhail G Golkovski
Affiliation:(1) the Center for Advanced Aerospace Materials, Pohang University of Science and Technology, 790-78 Pohang, Korea;(2) the Materials Science and Engineering Department, Pohang University of Science and Technology, USA;(3) the Applications of Industrial Accelerators, The Budker Institute of Nuclear Physics, 630090 Novosibirsk, Russia
Abstract:This study is concerned with the microstructural analysis and improvement of the hardness and wear resistance of Ti-6Al-4V surface-alloyed materials fabricated by a high-energy electron beam. The mixtures of TiC, TiN, or TiC + TiN powders and CaF2 flux were deposited on a Ti-6Al-4V substrate, and then the electron beam was irradiated on these mixtures. In the specimens processed with a flux addition, the surface-alloyed layers of 1 mm in thickness were homogeneously formed without defects and contained a large amount (over 30 vol pct) of precipitates such as TiC, TiN, (Ti x Al1−x )N, and Ti(C x N1−x ) in the martensitic or N-rich acicular α-Ti matrix. This microstructural modification, including the formation of hard precipitates and hardened matrices in the surface-alloyed layers, improved the hardness and wear resistance. Particularly in the surface-alloyed material fabricated by the deposition of TiN powders, the wear resistance was greatly enhanced to a level 10 times higher than that of the Ti alloy substrate. These findings suggested that surface alloying using high-energy electron-beam irradiation was economical and useful for the development of titanium-based surface-alloyed materials with improved hardness and wear resistance.
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