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| VAC与DMC共聚合制备正离子型无皂乳液 | |
| 引用本文： | 张书香,王金刚,闫良国,朱宏. VAC与DMC共聚合制备正离子型无皂乳液[J]. 合成橡胶工业, 2002, 25(6): 347-349 |
| 作者姓名： | 张书香 王金刚 闫良国 朱宏 |
| 作者单位： | 1. 济南大学,化工学院,山东,济南,250022 2. 济南大学,化学与环境工程学院,山东,济南,250022 3. 济南军区环境监测中心站,山东,济南,250002 4. 南京工业大学,材料学院,江苏,南京,210009 |
| 基金项目： | 山东省自然科学基金资助项目（项目编号:Y97B10033） |
| 摘 要： | 以偶氮二异丁基脒酸盐（AIBA）为引发剂，用乙酸乙烯酯（VAC）与甲基丙烯酰氧乙基三甲基氯化铵（DMC）单体进行无皂乳液聚合，制备了正离子型无皂乳液。结果表明，增加DMC单体的质量分数和采用连续加料方式能够提高乳液的总固物质量分数和稳定性，同时连续加料聚合可以得到均匀、粒径较小的粒子。 |
| 关 键 词： | VAC DMC 共聚合 制备 正离子型 无皂乳液 乙酸乙烯酯 甲基丙烯酰氧乙基三甲基氯化铵 稳定性 |
| 文章编号： | 1000-1255(2002)06-0347-03 |
Preparation of soap-free cationic emulsion copolymerization with VAC and DMC |
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| Zhang Shuxiang,Wang Jingang,Yan Liangguo,Zhu Hong. Preparation of soap-free cationic emulsion copolymerization with VAC and DMC[J]. China Synthetic Rubber Industry, 2002, 25(6): 347-349 | |
| Authors: | Zhang Shuxiang Wang Jingang Yan Liangguo Zhu Hong |
| Abstract: | The soap - free cationic emulsion copoly-merization of VAC and DMC was studied and the stability of latex and modality of particle with different mass fraction of DMC and different feeding methods of polymerization were researched. It was indicated that the increase of DMC and polymerization continuousmonomer feeding could increase the solid content and stability of latex, particle of well - proportioned and small diameter was obtained. |
| Keywords: | vinyl acetate DMC soap - free cationic emulsion stability |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |