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液氢容器真空夹层氢吸附剂研究进展
引用本文:刘磊,潘权稳,王博,赵钦宇,江龙,何远新,周伟明,甘智华.液氢容器真空夹层氢吸附剂研究进展[J].浙江大学学报(自然科学版 ),2022,56(11):2194-2203.
作者姓名:刘磊  潘权稳  王博  赵钦宇  江龙  何远新  周伟明  甘智华
作者单位:1. 浙江省制冷与低温技术重点实验室 浙江大学,浙江 杭州 3100272. 浙大城市学院 低温中心,浙江 杭州 3100153. 中车长江车辆有限公司 冷运装备研究所,湖北 武汉 4302124. 全国锅炉压力容器标准化技术委员会,移动式压力容器分技术委员会,上海 200030
基金项目:广东省重点领域研发计划资助项目(2021B0101300004); 国家自然科学基金资助项目(52006190)
摘    要:基于液氢容器高效氢吸附剂对使用方式、材料改性、性能评价和用量计算的需求,讨论真空夹层中的气体负荷来源和真空寿命,总结液氢容器常用氢吸附剂的种类、材料以及吸附性能研究方法.真空夹层主要的残余气体是材料放出的氢气,通过合理使用吸附剂可以显著延长容器寿命.根据吸气机理可将氢吸附剂分为低温吸附剂、金属氧化物、离子交换沸石分子筛和非蒸散型吸气剂4类,并从实验测试和理论模型2个方面总结了吸附性能的研究方法.

关 键 词:氢能  液氢容器  真空多层绝热  氢吸附剂  吸附性能

Progress of hydrogen adsorbents in vacuum jacket of liquid hydrogen vessels
Lei LIU,Quan-wen PAN,Bo WANG,Qin-yu ZHAO,Long JIANG,Yuan-xin HE,Wei-ming ZHOU,Zhi-hua GAN.Progress of hydrogen adsorbents in vacuum jacket of liquid hydrogen vessels[J].Journal of Zhejiang University(Engineering Science),2022,56(11):2194-2203.
Authors:Lei LIU  Quan-wen PAN  Bo WANG  Qin-yu ZHAO  Long JIANG  Yuan-xin HE  Wei-ming ZHOU  Zhi-hua GAN
Abstract:The sources of gas load and vacuum life of the vacuum jacket were discussed based on the requirements of usage mode, material modification, performance evaluation and amount calculation for efficient hydrogen adsorbent in liquid hydrogen vessels. The types and ingredients of common hydrogen adsorbents and research methods of adsorption commonly used in liquid hydrogen containers were summarized. The hydrogen released by the materials was the main residual gas in the vacuum jacket and the vessel life can be significantly extended by the rational use of adsorbents. The hydrogen adsorbents can be classified into four categories according to adsorption mechanism: low temperature adsorbents, metal oxides, ion exchanged zeolite molecular sieves and non-evaporable getters. The research methods of adsorption performance were summarized in aspects of both experimental test and theoretical model.
Keywords:hydrogen energy  liquid hydrogen vessel  vacuum multilayer insulation  hydrogen adsorbent  adsorption performance  
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