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Martensitic phase transformations in IMI 550 (Ti-4Al-4Mo-2Sn-0.5 Si)
Authors:K K Kharia  H J Rack
Affiliation:(1) Department of Ceramic and Materials Engineering, Clemson University, 29634 Clemson, SC
Abstract:The influence of solution-treatment temperature on the martensitic phase transformations observed in IMI 550 (Ti−4Al−4Mo−2Sn−0.5Si) has been investigated. When solution treatment is conducted at temperatures above 1233 K, a hexagonal martensite α′ is formed on rapid cooling. However solution treatment at temperatures between 1233 and 1123 K results in the formation of an orthorhombic martensite (α″) on rapid cooling. Finally, below 1123 K, the β phase is stable—no martensitic transformation occurs on rapid cooling. this transition from 
$$\alpha ' \to \alpha _{primary} {\text{  +  (}}\alpha {\text{  +  }}\beta _{{\text{retained}}} ) \to {\text{ }}\alpha _{{\text{primary}}} {\text{  +  (}}\alpha {\text{  +  }}\beta _{retained} ) \to {\text{ }}\alpha _{{\text{primary}}} {\text{  +  }}\beta _{metastable} {\text{  +  }}\omega $$
with decreasing solution-treatment temperature, is shown to be a result of alloy partitioning during solution treatment. Crystallographic analysis indicates that the transition in the martensite crystal structure with decreasing solution-treatment temperature is related to chemical short-range ordering (CSRO) in the high-temperature β phase.
Keywords:
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