| 四种新喹啉叠氮化合物的合成及其与某些金属离子的反应 |
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| 引用本文： | 汤园平 沈含熙. 四种新喹啉叠氮化合物的合成及其与某些金属离子的反应[J]. 化学试剂, 1997, 19(1): 1-4,14 |
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| 作者姓名： | 汤园平 沈含熙 |
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| 作者单位： | 南开大学化学系!天津300071上海医科大学(汤园平)，南开大学化学系!天津300071(沈含熙) |
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| 基金项目： | 国家自然科学资金博士点赞助 |
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| 摘 要： | 合成了４种新喹啉叠氮化合物，３－（喹啉偶氮）－１－三氮烯苯甲酸钠（ＱＴＢＡＳ），对硝基重氨基喹啉偶氮喹啉（ＮＱＡＱ）对氯重氮氨基喹啉偶氮喹啉（ＣＱＡＱ），４－（喹啉偶氮喹啉）－１－三氮烯苯磺酸钠（ＱＴＢＳＡ），通过红外和元素分析验证了它们的结构，并研究了其物理和化学性质，这是一类测定铜，钴，镍的选择性新试剂。
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| 关 键 词： | QTBAS NQAQ CQAQ QTBSA 喹啉 叠氮化合物 显色剂 |
The synthesis of four new quinoline azide compounds and their reaction with metal ions |
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| Tang Yuanping,Shen Hanxi. The synthesis of four new quinoline azide compounds and their reaction with metal ions[J]. Chemical Reagents, 1997, 19(1): 1-4,14 |
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| Authors: | Tang Yuanping Shen Hanxi |
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| Abstract: | Four new quinoline azide compounds have been synthesized: sodium 3-(quinolylazoquinoline )-1-triazene benzoate (QTBAS), p-nitrodiazoaminoquinolylazoquinoline (NQAQ ), pwchlorodiazoaminoquinolylazoquinoline (CQAQ ), and sodium 4-(quinolylazoquinoline )-1-triazene benzene sulfonate (QTBSA ). Their structures were identified by infrared spectra, elemental analysis, etc. Their physical and chemical properties were also investigated. These four reagents can be used to determine Co2+ . Cu2+.Ni2+ by spectrophotometry. The methods are sensititive and selective. |
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| Keywords: | QTBAS NQAQ CQAQ QTBSA spectrophotometry |
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