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Response to oxygen and chemical properties of SnO2 thin-film gas sensors
Authors:Bogus?awa Adamowicz  Weronika Izydorczyk  Andrzej Klimasek  Janusz ?ywicki
Affiliation:a Institute of Electronics, Silesian University of Technology, Akademicka 16, 44-100 Gliwice, Poland
b Department of Applied Physics and Department of Optoelectronics, Institute of Physics, Silesian University of Technology, Krzywoustego 2, 44-100 Gliwice, Poland
c High-Tech International Services, Rome, Italy
Abstract:The measurements of the response—in terms of the conductance changes—to oxygen adsorption of tin dioxide (SnO2) thin-film-based gas sensors were performed. The sensing SnO2 layers were obtained by means of the rheotaxial growth and thermal oxidation (RGTO) method. The sensor responses were measured under a dry gas flow containing oxygen in nitrogen, within the range of temperature from 25 to 540 °C. For comparison, similar studies were performed for a commercial SnO2 thick-film (TGS 812) gas sensor.The in-depth profiles of the chemical composition of the RGTO SnO2 layers were determined from the scanning Auger microprobe experiment. The changes in concentration ratios [O]/[Sn] and [C]/[Sn] from the near-surface region towards the grain bulk were shown.
Keywords:Tin dioxide   RGTO technique   Oxygen adsorption   Surface electronic properties   Solid-state gas sensors   Auger electron spectroscopy
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