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表面涂覆CeO2对Fe—23Cr—5Al合金上Al2O3膜生长应力的影响
引用本文:李美栓,钱余海,辛丽,周龙江.表面涂覆CeO2对Fe—23Cr—5Al合金上Al2O3膜生长应力的影响[J].腐蚀科学与防护技术,2000,12(1):1-5.
作者姓名:李美栓  钱余海  辛丽  周龙江
作者单位:中国科学院金属腐蚀与防护研究所,金属腐蚀与防护国家重点实验室,沈阳,110015
基金项目:中国科学院资助项目,59701010,
摘    要:研究了表面涂覆CeO2对Fe-23Cr-5Al合金900℃和1000℃下形成的Al2O3膜生长应力的影响。涂覆CeO2增大了合金的氧化速率,促进了Al2O3膜的起皱同时也增大了Al2O3膜的生长应力。涂覆CeO2表面形成的起皱的Al2O3膜在冷却过程中剥落量较少;而在真空保温过程中应力不容易释放。认为表面涂覆CeO2对Fe-23Cr-5Al的抗氧化并不能起到改善作用。

关 键 词:应力  氧化膜  稀土效应  高温氧化  生长应力

INFLUENCE OF SUPERFICIALLY APPLIED CERIA ON THE GROWTH STRESSES IN ALUMINA SCALES
LI Meishuan,QIAN Yuhai,XIN Li,ZHOU Longjiang.INFLUENCE OF SUPERFICIALLY APPLIED CERIA ON THE GROWTH STRESSES IN ALUMINA SCALES[J].Corrosion Science and Protection Technology,2000,12(1):1-5.
Authors:LI Meishuan  QIAN Yuhai  XIN Li  ZHOU Longjiang
Abstract:The influence of superficially applied CeQ on the growth stresses in A1203 scales forned on Fe- 23Cr-5A1-0.2113 alloy at 900°C and 1000°C has been investigated by using a modified deflection technique. CeQ coating increased the mass gain of the alloy, pmted the convolution of A1203 scale, and increased the graYth oxide stresses. The creep of the alloy has a less effect on the relaxation of the growth stress in the convoluted scale than on that in the plane scale. Although less spallation of the convoluted scale during cooling, CeQ coating had no clear beneficial effect on the oxidation resistance of Fe-23Cr-5A1 alloy.
Keywords:stress  oxide scale  REE  oxidation
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