| 关于立方型状态方程的若干评述和讨论 |
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| 引用本文： | 云志,包宗宏,史美仁,时钧. 关于立方型状态方程的若干评述和讨论[J]. 陶瓷科学与艺术, 1998, 0(3) |
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| 作者姓名： | 云志 包宗宏 史美仁 时钧 |
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| 作者单位： | 南京化工大学化学工程系 |
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| 摘 要： | 对在状态方程，尤其是立方型状态方程，研究与开发过程中的几个重要问题，从若干层面进行了评述和讨论。评价了统计力学在开发状态方程中的作用，并指出了其局限性。通过综述温度函数的发展状况，给出了温度函数仍然是纯经验性等看法。对混合规则的发展状况以及各种不同类型的混合规则进行了评述和比较。
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| 关 键 词： | 状态方程 统计热力学 温度函数 混合规则 |
COMMENT ON EQUATION OF STATE |
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| Yun Zhi Bao Zhonghong Shi Meiren Shi Jun. COMMENT ON EQUATION OF STATE[J]. Ceramics Science & Art, 1998, 0(3) |
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| Authors: | Yun Zhi Bao Zhonghong Shi Meiren Shi Jun |
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| Affiliation: | Yun Zhi Bao Zhonghong Shi Meiren Shi Jun Department of Chemical Engineering,Nanjing University of Chemical Technology,Nanjing,210009,China |
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| Abstract: | Several important problems in the processes of developing equations of state(EOS),especially cubic EOS,are discussed and reviewed.The function and limits of statistical thermodynamics in the developing of EOS are valued.The developing of temperature functions in EOS and their actions on EOS are reviewed with the indication that the various temperature functions are total experimental.The mixing rules used for the parameters in EOS are compared and the developing of the mixing rules are also reviewed. |
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| Keywords: | equation of state statistical thermodynamics temperature function mixing rule |
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