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山梨糖醇类及有机磷酸盐类成核剂对聚丙烯性能的影响
引用本文:鲁圣军,何敏,于杰,张敏敏.山梨糖醇类及有机磷酸盐类成核剂对聚丙烯性能的影响[J].塑料科技,2009,37(10).
作者姓名:鲁圣军  何敏  于杰  张敏敏
作者单位:1. 贵州大学材料与冶金学院,贵州,贵阳,550003;国家复合改性聚合物材料工程技术研究中心,贵州,贵阳,550014
2. 国家复合改性聚合物材料工程技术研究中心,贵州,贵阳,550014
基金项目:国家科技支撑计划课题,贵州省科学基金项目 
摘    要:利用力学性能测试、偏光显微镜、光电雾度仪及差热分析仪分别考察了山梨糖醇类成核剂(TM-3)和有机磷酸盐类成核剂(NA-21)对聚丙烯(PP)透明性、结晶性能及力学性能的影响。结果表明:NA-21和TM-3对PP均有明显增透的作用;NA-21比TM-3更能提高PP的结晶温度,而TM-3比NA-21更能提高PP的结晶度;TM-3的加入能明显提高PP的冲击强度,而NA-21的加入能明显提高PP的拉伸强度。

关 键 词:聚丙烯  山梨糖醇  有机磷酸盐  成核剂  性能

Effect of Sorbitol and Organic Phosphate Nucleating Agents on Properties of Polypropylene
Lu Shengjun,He Min,Yu Jie,Zhang Minmin.Effect of Sorbitol and Organic Phosphate Nucleating Agents on Properties of Polypropylene[J].Plastics Science and Technology,2009,37(10).
Authors:Lu Shengjun  He Min  Yu Jie  Zhang Minmin
Abstract:The effect of nucleating agent,such as sorbitol (TM-3) and organic phosphate (NA-21),on the crystallization,transparency and mechanical properties of PP was investigated by DSC,PLM,photoelectricity opacimeter and mechanical properties test. The results show that:both NA-21 and TM-3 have positive effect on the transparency of PP; after the addition of NA-21,the increment of crystallization temperature is bigger and the increment of crystallinity is smaller for PP than those after the addition of TM-3; the addition of TM-3 and NA-21 could increase obviously the impact strength and tensile strength of PP respectively.
Keywords:Polypropylene  Sorbitol  Organic phosphate  Nucleating agent  Property
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