Measurement of the intramolecular fluctuations of random coil polymers by photon correlation spectroscopy |
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Authors: | J. Hendrix B. Saleh K. Gnädig L. De Maeyer |
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Affiliation: | Max-Planck Institut für Biophysikalische Chemie, D-3400 Göttingen, Germany |
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Abstract: | The correlation function of light scattered from dilute solutions of large molecular weight polystyrene has been measured using a photon-counting digital autocorrelator. By determining the effective spectral broadening and the change in the spectral profile due to intramolecular fluctuations, the range of validity of the Zimm-Rouse model of intramolecular dynamics has been examined. |
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