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Measurement of the intramolecular fluctuations of random coil polymers by photon correlation spectroscopy
Authors:J. Hendrix  B. Saleh  K. Gnädig  L. De Maeyer
Affiliation:Max-Planck Institut für Biophysikalische Chemie, D-3400 Göttingen, Germany
Abstract:The correlation function of light scattered from dilute solutions of large molecular weight polystyrene has been measured using a photon-counting digital autocorrelator. By determining the effective spectral broadening and the change in the spectral profile due to intramolecular fluctuations, the range of validity of the Zimm-Rouse model of intramolecular dynamics has been examined.
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