| 正构烷烃加氢异构化反应机理的研究进展 |
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| 引用本文： | 金昌磊,马波,张喜文,凌凤香,张志智. 正构烷烃加氢异构化反应机理的研究进展[J]. 工业催化, 2008, 16(1): 1-4 |
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| 作者姓名： | 金昌磊 马波 张喜文 凌凤香 张志智 |
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| 作者单位： | 辽宁石油化工大学石油化工学院,辽宁,抚顺,113001;中国石化抚顺石油化工研究院,辽宁,抚顺,113001;辽宁石油化工大学石油化工学院,辽宁,抚顺,113001;中国石化抚顺石油化工研究院,辽宁,抚顺,113001 |
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| 基金项目： | 中国石油化工集团公司资助项目 |
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| 摘 要： | 综述了近年来正构烷烃在分子筛为载体的双功能催化剂上加氢异构化反应机理的研究进展，介绍了单分子机理、双分子机理、孔口机理及锁匙机理，并展望了反应机理在制备新型催化剂领域的应用前景。
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| 关 键 词： | 石油化学工程 加氢异构化反应 单分子机理 双分子机理 孔口机理 锁匙机理 |
| 文章编号： | 1008-1143（2008）01-0001-04 |
| 收稿时间： | 2007-09-11 |
| 修稿时间： | 2007-09-11 |
Advances in studies on mechanisms for n-alkane hydroisomerization |
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| JIN Changlei,MA Bo,ZHANG Xiwen,LING Fengxiang,ZHANG Zhizhi. Advances in studies on mechanisms for n-alkane hydroisomerization[J]. Industrial Catalysis, 2008, 16(1): 1-4 |
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| Authors: | JIN Changlei MA Bo ZHANG Xiwen LING Fengxiang ZHANG Zhizhi |
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| Affiliation: | 1.College of Petrochemical Engineering, Liaoning University of Petroleum ＆ Chemical Technology, Fushun 113001, Liaoning, China; 2.Sinopec Fushun Research Institute of Petroleum ＆ Petrochemicals, Fushun 113001, Liaoning, China |
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| Abstract: | Latest advances in studies on mechanisms for hydroisomerizaton of n-alkane over bifunctional catalysts supported on zeolites, including monomolecular and bimolecular reaction mechanisms, pore mouth mechanism and key-lock mechanisms, were reviewed. The prospects for application of these mechanisms in development of new catalysts were outlined. |
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| Keywords: | petrochemical technology hydroisomerization reaction monomolecular mechanism bimo- lecular mechanism pore mouth mechanism key-lock mechanism |
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