| 化工热力学剩余性质推导 |
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| 引用本文： | 胡光辉,潘湛昌,魏志钢. 化工热力学剩余性质推导[J]. 广东化工, 2011, 38(5): 254+235-254,235 |
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| 作者姓名： | 胡光辉 潘湛昌 魏志钢 |
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| 作者单位： | 广东工业大学,轻工化工学院,广东,广州,510006 |
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| 基金项目： | 广东工业大学轻工化工学院质量工程培育项目 |
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| 摘 要： | 介绍了剩余性质的概念及其数学表达,在以压力、温度为独立变量的剩余性质公式的基础上,推导了以温度、体积为独立变量的剩余性质公式。由于多数热力学状态方程以压力为显函数,即p=p（T,V）,因此推导以温度、体积为独立变量的剩余性质公式具有应用意义。
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| 关 键 词： | 化工热力学 剩余性质 独立变量 |
Deduction of Residual Property of Chemical Thermodynamics |
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| Hu Guanghui,Pan Zhanchang,Wei Zhigang. Deduction of Residual Property of Chemical Thermodynamics[J]. Guangdong Chemical Industry, 2011, 38(5): 254+235-254,235 |
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| Authors: | Hu Guanghui Pan Zhanchang Wei Zhigang |
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| Affiliation: | (Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China) |
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| Abstract: | It was introduced that concept of residual property and its mathematic expression.Based on equations of residual property with pressure and temperature as independent variable,we deduced the expression of residual property with temperature and volume as independent variable.Because of pressure as a explicit function of temperature and volume in most thermodynamic state equations,that was p=p(T,V),it was meaningful to deduce formula of residual property with temperature and volume as independent variable. |
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| Keywords: | chemical thermodynamics residual property independent variable |
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