| 无溶剂条件下微波辅助合成硫氰酸酯类化合物 |
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| 引用本文： | 徐利亚,宋芳锐. 无溶剂条件下微波辅助合成硫氰酸酯类化合物[J]. 广东化工, 2011, 38(5): 303-304,308 |
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| 作者姓名： | 徐利亚 宋芳锐 |
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| 作者单位： | 河北大学,药学院,河北,保定,071002 |
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| 摘 要： | 芳基硫氰酸酯是重要的有机合成中间体,得到越来越广泛的应用。文章研究了无溶剂条件下微波辅助合成的方法,用此方法合成了一系列的芳基硫氰酸酯。反应在几分钟内就能完成,并且收率大多在80%以上。该方法操作简单,反应时间短,产率高,环境友好,符合绿色化学的发展要求。
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| 关 键 词： | 聚乙二醇 无溶剂 微波辐射 硫氰酸酯 |
Solvent-Free and Microwave-assisted Synthesis of Thiocyanates |
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| Xu Liya,Song Fangrui. Solvent-Free and Microwave-assisted Synthesis of Thiocyanates[J]. Guangdong Chemical Industry, 2011, 38(5): 303-304,308 |
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| Authors: | Xu Liya Song Fangrui |
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| Affiliation: | (College of Pharmacy,Hebei University,Baoding 071002,China) |
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| Abstract: | Aromatic thiocyanates were important intermediates in organic synthesis,and are more widely used.The paper study the solvent-free conditions,microwave assisted synthesis method,and we synthesized a series of aromatic thiocyanates.The reaction can be done in three minutes.Yield most can reach up to 80 %.The method is simple,efficient,environmentally friendly,and meets the requirements of the development of green chemistry. |
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| Keywords: | PEG400 without solvent microwave irradiation thiocyanate |
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